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Flash Point & Flammability Reference

Searchable table of flash points, autoignition temperatures, LEL, and UEL for 50+ chemicals. NFPA 30 classification (Class IA through IIIB).

Reviewed by Christopher FloiedPublished Updated

This free online flash point & flammability reference provides instant results with no signup required. All calculations run directly in your browser — your data is never sent to a server. Supports both metric (SI) and imperial units with built-in unit selection dropdowns on every input field, so you can work in whatever units your problem provides. Designed for engineering students and professionals working through coursework, design projects, or quick reference calculations.

Flash Point & Flammability Reference

Flash point, autoignition temperature, LEL, and UEL for 50+ chemicals. NFPA 30 classification. Click headers to sort.

Class IA: FP < -18°CClass IB: -18 to 23°CClass II: 38-60°CClass III: >60°C

50 chemicals shown

ChemicalFormulaFlash Point (°C)Autoignition (°C)LEL (% vol)UEL (% vol)Class
HydrogenH₂-253500475Class IA
Methane (Natural Gas)CH₄-188537515Class IA
PropaneC₃H₈-1044702.19.5Class IA
n-ButaneC₄H₁₀-604051.88.4Class IA
IsopentaneC₅H₁₂-514201.47.6Class IA
PentaneC₅H₁₂-492601.47.8Class IA
Diethyl EtherC₄H₁₀O-451601.936Class IA
Gasoline (avg.)C₄-C₁₂-432461.47.6Class IB
AcetaldehydeC₂H₄O-39175460Class IA
FuranC₄H₄O-363902.314.3Class IA
AcroleinC₃H₄O-262352.831Class IA
HexaneC₆H₁₄-222251.17.5Class IB
Ethylene OxideC₂H₄O-204293100Class IA
AcetoneC₃H₆O-204652.512.8Class IB
CyclohexaneC₆H₁₂-202601.38Class IB
TetrahydrofuranC₄H₈O-14321211.8Class IB
BenzeneC₆H₆-114981.27.8Class IB
MEK (Butanone)C₄H₈O-94041.411.4Class IB
Ethyl AcetateC₄H₈O₂-4426211.5Class IB
HeptaneC₇H₁₆-42041.056.7Class IB
AcetonitrileCH₃CN2524316Class IB
TolueneC₇H₈44801.17.1Class IB
MethanolCH₃OH11385636.5Class IB
Isopropanol (IPA)C₃H₇OH12399212.7Class IB
EthanolC₂H₅OH133653.319Class IB
OctaneC₈H₁₈132060.86.5Class IB
PyridineC₅H₅N174821.710.6Class IB
Xylene (mixed)C₈H₁₀2746417Class IC
ChlorobenzeneC₆H₅Cl285901.89.6Class IC
StyreneC₈H₈314900.96.8Class IC
n-ButanolC₄H₉OH353431.411.2Class IC
NitromethaneCH₃NO₂354187.3Class IC
Kerosene (Jet A)C₈-C₁₆382100.75Class II
Acetic AcidCH₃COOH39427419.9Class II
Formic AcidCH₂O₂504341857Class II
Diesel FuelC₁₂-C₂₅522100.67.5Class II
FormaldehydeCH₂O85430773Class IIIA
Dimethyl SulfoxideC₂H₆OS953002.642Class IIIA
Propylene GlycolC₃H₈O₂993712.612.5Class IIIA
Ethylene GlycolC₂H₆O₂1113983.2Class IIIB
GlycerolC₃H₈O₃160370Class IIIB
Lube Oil (typical)200360Class IIIB
AmmoniaNH₃6511528Non-flash
Carbon MonoxideCO60912.574Gas
EthyleneC₂H₄4502.736Gas
AcetyleneC₂H₂3052.5100Gas
Sulfuric AcidH₂SO₄Non-flammable
ChloroformCHCl₃1000Non-flammable
Hydrogen SulfideH₂S2604.346Gas
ChlorineCl₂Oxidizer

Flammability Range (LEL–UEL) by Chemical

Each bar spans the lower to upper explosive limit (% vol in air).

Tip: hover to read values, click to pin a point for export

LEL = Lower Explosive Limit (minimum % concentration to sustain combustion) | UEL = Upper Explosive Limit (maximum % to sustain combustion) | Autoignition = temperature at which spontaneous ignition occurs without external ignition source. All values are approximate and may vary with conditions. Always consult SDS for safety-critical applications.

How to Use This Calculator

1

Enter your input values

Fill in all required input fields for the Flash Point & Flammability Reference. Most fields include unit selectors so you can work in your preferred unit system — metric or imperial, whichever matches your problem.

2

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Double-check that all values are correct and that you have selected the right units for each field. Incorrect units are the most common source of calculation errors and can produce results that are off by factors of 2, 10, or more.

3

Read the results

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4

Explore parameter sensitivity

Try adjusting individual input values to see how the output changes. This is a quick and effective way to develop intuition about how different parameters influence the result and to identify which inputs have the largest effect.

Formula Reference

Flash Point & Flammability Reference Formula

See calculator inputs for the governing equation

Variables: All variables and their units are labeled in the calculator interface above. Input fields accept values in multiple unit systems — select your preferred unit from the dropdown next to each field.

When to Use This Calculator

  • Use the Flash Point & Flammability Reference when solving homework or exam problems that require quick numerical verification of your hand calculations — instant feedback helps identify arithmetic errors before they propagate.
  • Use it during the early design phase to rapidly iterate on parameters and narrow down feasible configurations before committing time to detailed finite element simulations or full design packages.
  • Use it when reviewing a colleague's calculation or checking a vendor's data sheet for plausibility — a quick sanity check can prevent costly downstream errors.
  • Use it to generate reference data for a technical report or presentation without manual computation, ensuring consistent, reproducible numbers throughout the document.
  • Use it in the field when a quick estimate is needed and a full engineering software package is not available.

About This Calculator

The Flash Point & Flammability Reference is a precision engineering calculation tool designed for students, engineers, and technical professionals. Searchable table of flash points, autoignition temperatures, LEL, and UEL for 50+ chemicals. NFPA 30 classification (Class IA through IIIB). All calculations are performed using established engineering formulas from the relevant scientific literature and standards. Inputs support both metric (SI) and imperial unit systems, with unit conversion handled automatically — simply select your preferred unit from the dropdown next to each field. Results are computed instantly in the browser without sending data to a server, ensuring both speed and privacy. This calculator is intended as a supplementary tool for learning and design exploration; always verify results against authoritative references for safety-critical applications.

The Theory Behind It

Flash point is the lowest temperature at which a liquid produces enough vapor to form an ignitable mixture with air near its surface, as measured by a standardized test (typically closed-cup methods like Pensky-Martens or Tag closed tester). Flash point is a key safety parameter for flammable liquid storage, transport, and handling. Classifications include: Class IA (< 22.8°C / 73°F, highly flammable, very low flash point — gasoline, ether), Class IB (22.8-37.8°C / 73-100°F — ethanol, methanol, acetone), Class IC (37.8-60°C / 100-140°F — kerosene, turpentine), Class II (60-93°C / 140-200°F — diesel fuel, fuel oil), Class IIIA (93-200°C / 200-392°F — high flash oils), Class IIIB (> 200°C / 392°F — lubricating oils, heavy oils). OSHA, NFPA, DOT, and IATA use these classifications for safety regulations. Flash point is distinct from auto-ignition temperature (the temperature at which a substance spontaneously ignites without an external flame) and from fire point (the temperature at which sustained combustion occurs, usually a few degrees above flash point). Reference tables list flash points for hundreds of common chemicals, fuels, and solvents.

Real-World Applications

  • Chemical storage and handling: determine appropriate storage classification, ventilation requirements, and electrical classification (Class 1 Division hazardous areas) for flammable liquid storage.
  • Transport classification: DOT, IATA, and IMDG regulations use flash point to categorize shipping hazard classes and container requirements.
  • Fire and safety planning: emergency response procedures depend on flash point to anticipate vapor hazards and appropriate fire suppression techniques.
  • Fuel specification and blending: gasoline, diesel, and aviation fuels have minimum flash point requirements for safety; refineries measure and specify flash point on product certificates.
  • Industrial hygiene: exposure limits and ventilation calculations consider vapor pressure (related to flash point) to ensure worker safety around flammable liquids.

Frequently Asked Questions

What is flash point?

The lowest temperature at which a liquid produces enough vapor to ignite when exposed to an ignition source. Measured by standardized closed-cup tests (Pensky-Martens, Tag, Setaflash) or open-cup tests (Cleveland). Flash point is a key safety parameter for flammable liquids — substances with low flash points are hazardous at ordinary ambient temperatures.

What are the flammable liquid classifications?

NFPA classifications: Class IA (flash point < 22.8°C, boiling point < 37.8°C) — highly flammable, e.g., diethyl ether, propylene oxide. Class IB (< 22.8°C, BP ≥ 37.8°C) — most solvents like acetone, methanol, ethanol, toluene. Class IC (22.8-37.8°C) — styrene, turpentine. Class II (37.8-60°C) — diesel, kerosene, JP-5. Class IIIA (60-93°C) and Class IIIB (> 93°C) — lubricating oils and high-flash materials.

What's the difference between flash point and auto-ignition temperature?

Flash point requires an external ignition source (open flame or spark); vapor alone ignites briefly and then extinguishes. Auto-ignition temperature is the temperature at which a substance spontaneously ignites without external flame, sustained combustion begins on contact with a hot surface. Auto-ignition is typically 100-300°C above flash point for most hydrocarbons.

What's the flash point of gasoline?

Gasoline has an extremely low flash point of approximately −43°C (−45°F), meaning vapor is flammable at any ambient temperature above that. This is why gasoline vapors are dangerous in ordinary conditions and why spark-free handling procedures, proper grounding, and explosion-proof electrical equipment are required around gasoline storage.

How is flash point measured?

Standard test methods include ASTM D93 (Pensky-Martens closed cup, for fuels and viscous liquids), ASTM D56 (Tag closed cup, for volatile liquids), ASTM D3828 (Setaflash closed cup, small-sample rapid method), ASTM D1310 (Tag open cup), and ASTM D92 (Cleveland open cup, for heavy oils). Closed-cup methods generally give values 5-10°C lower than open-cup because vapor is more concentrated.

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References & Further Reading

Wikipedia

Standards & Organizations

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